Abstract：Ion-molecule reactions of disbstituted benzene with ion system of acetone and deuterium-labelled acetone under chemical ionization conditions were examined and the fragmentation reactions of the adduct ions formed by the ion-molecule reactions were studied using collision- induced dissociation (CID) technique. It was found that the electron- releasing groups favored the adduct eactions, whereas the electron- withdrawing groups did not. The position and properties of substituted groups affected the relative abundance of the adduct ions. The fragmentation reaction of the adduct ion formed by ortho- phenylenediamine with acetyl ion was simlar to the reductive alkylation reaction of amine in condensed phase.
李智立,刘淑莹. 气相中双取代苯在丙酮离子体系中的加合反应研究[J]. 化学学报, 2000, 58(4): 432-437.
Li Zhili;Liu Shuying. Studies on the adduct reaction of disubstituted benzenes with ion system of acetone in gas pahse. Acta Chimica Sinica, 2000, 58(4): 432-437.